Like RoverALex said, the pulley nut is the worst of the job. I am trying to wrack my brain to remember how I did mine, yonks ago, and you basically need to pull the radiator, remove the fan/fan belts/pulley, distributor, (I think) the water pump and then the cover. You need to note the bolt length/positions for reassembly.
The long bolts go into the block, if you are lucky, it will have broken proud of the block, meaning it is reasonably easy to remove. Start by soaking it with a penetrating oil, I use a mix of ATF and Lacquer Thinners and the more for longer, the better. Then, if you can get access, grab it with a vise-grip and wiggle it to and fro and it will come out, eventually. If you have the machine and the skill, you can place a nut over the stub and weld it on, as it cools, the cooling action causes it to shrink ever so slightly and the heat helps loosen it, too. Quite often, with the penetrating oil, you end up turning it out by hand.
When you assemble it all, use liberal amounts of Never-Seez or Coppa-Slip to prevent seizure after assembly, and some of the bolts go into the water jacket of the block and they need a sealer on the thread.
If I have got anything wrong or left anything out, please correct/edit for me.